Journal of Petrology | Volume 29 | Number 3 | Pages 699-729 | 1988
© Oxford University Press 1988
research-article |
Crystallization Conditions of the Sybille Monzosyenite, Laramie Anorthosite Complex, Wyoming
1Department of Earth and Space Sciences, State University of New York Stony Brook, NY 11794-2100
2Department of Geology and Geophysics, University of Wyoming Laramie WY 82071
Received September 30, 1987; Revised February 2, 1988; ABSTRACT
The Sybille Monzosyenite, associated with the Laramie Anorthosite Complex, consists of rocks ranging in composition from monzogabbro to monzosyenite. There is a continuous range of mineral compositions with plagioclase varying from An45 to An25 and olivine from Fa75 to Fa98 Strongly ternary (Or, Ab, An all > 10 mol%) feldsparspresently mesoperthitesare found in all rock types and define a continuous trend also in the feldspar ternary system. The mineral compositions suggest that the rock types of the Sybille Monzosyenite could be part of a single differentiation sequence; contamination of the later units by assimilation of, or admixture of partial melts from, country rock is also likely. Original magmatic temperatures of approximately 9501050°C are indicated by estimated original compositions for pyroxenes and feldspars; pressure was near 3 kb, as indicated by the most magnesian olivine that coexists with quartz. Oxygen fugacity of crystallization is estimated as 1.5 to 2.0 log units below FMQ by using the displaced equilibrium: SiO2 + 2Fe2TiO3 = 2FeTiO3 + Fe2SiO4. Such oxygen fugacities are consistent with the occurrence of graphite and CO2-rich fluid inclusions, which suggest that crystallization took place in the presence of a CO2 vapor phase. Temperatures indicated by the present mineral assemblages show that all geothermometers used were reset during cooling, first by intergrain and then by intragrain processes.
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