Journal of Petrology | Volume 44 | Number 5 | Pages 867-900 | 2003
© Oxford University Press 2003
Temperatures of Granulite-facies Metamorphism: Constraints from Experimental Phase Equilibria and Thermobarometry Corrected for Retrograde Exchange
1 DEPARTMENT OF GEOLOGY AND GEOPHYSICS, UNIVERSITY OF CALGARY, CALGARY, AB, T2N 1N4, CANADA
2 DEPARTMENT OF EARTH AND ATMOSPHERIC SCIENCES, UNIVERSITY OF ALBERTA, EDMONTON, AB, T6G 2E3, CANADA
3 DEPARTMENT OF GEOLOGY AND EARTH SYSTEM SCIENCE INTERDISCIPLINARY CENTRE, UNIVERSITY OF MARYLAND, COLLEGE PARK, MD 20742, USA
4 DEPARTMENT OF GEOLOGICAL SCIENCES, THE UNIVERSITY OF TEXAS AT AUSTIN, AUSTIN, TX 78701, USA
Telephone: 403-220-3263. Fax: 403-284-0074. E-mail: pattison{at}ucalgary.ca
This study assesses temperatures of formation of common granulites by combining experimental constraints on the PT stability of granulite-facies mineral associations with a garnetorthopyroxene (GrtOpx) thermobarometry scheme based on Al-solubility in Opx, corrected for late FeMg exchange. We applied this scheme to 414 granulites of mafic, intermediate and aluminous bulk compositions. Our findings suggest that granulites are much hotter than traditionally assumed and that the PT conditions of the amphibolitegranulite transition portrayed in current petrology textbooks are significant underestimates by over 100°C. For aluminous and intermediate granulites, mean corrected temperatures based on our method are 890 ± 17 and 841 ± 11°C, respectively (uncertainties reported as 95% confidence limits on the mean), consistent with minimum temperatures for orthopyroxene production by fluid-absent partial melting in these bulk compositions. In contrast, mean temperatures based on GrtOpx FeMg exchange equilibria, using the same thermodynamic data, are 732 ± 22 and 723 ± 11°C, respectively, well below the minimum temperatures for Opx stability. For mafic granulites, the mean corrected temperature using our method is 816 ± 12°C, similar to the mean temperature of 793 ± 13°C from FeMg exchange. Reasons for the differences between the mafic granulites and aluminousintermediate granulites are unclear but may be due to the lower Al concentrations in Opx in the mafic rocks and possible deficiencies in the thermodynamic modelling of these low concentrations. We discuss a number of well-known granulite terrains in the context of our findings, including the Adirondacks, the Acadian granulites of New England, the incipient charnockites of southern India and Sri Lanka, and the Kerala Khondalite Belt. Our findings carry implications for thermotectonic models of granulite formation. A computer program to perform our thermobarometry calculations, RCLC, is available from the Journal of Petrology website at http://www.petrology.oupjournals.org or from the authors at http://www.geo.ucalgary.ca/~pattison/drm_pattison-rclc.htm.
KEY WORDS: granulite-facies metamorphism; thermobarometry; garnet; orthopyroxene
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