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Journal of Petrology Advance Access originally published online on May 28, 2007
Journal of Petrology 2007 48(8):1471-1494; doi:10.1093/petrology/egm026
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© The Author 2007. Published by Oxford University Press. All rights reserved. For Permissions, please e-mail: journals.permissions@oxfordjournals.org

Variations in Melt Productivity and Melting Conditions along SWIR (70°E–49°E): Evidence from Olivine-hosted and Plagioclase-hosted Melt Inclusions

L. Font1,*, B. J. Murton1, S. Roberts1 and A. G. Tindle2

1National Oceanography Centre, University of Southampton, European Way, Southampton SO14 3ZH, UK
2Department of Earth Sciences, The Open University, Walton Hall, Milton Keynes MK7 6AA, UK

RECEIVED FEBRUARY 25, 2005; ACCEPTED APRIL 25, 2007


    ABSTRACT
 TOP
 ABSTRACT
 INTRODUCTION
 TECTONIC SETTING AND SAMPLING
 PETROGRAPHY AND MINERAL...
 ANALYTICAL TECHNIQUES
 PILLOW RIM GLASS AND...
 INTERPRETATION
 CONCLUSIONS
 SUPPLEMENTARY DATA
 REFERENCES
 
Melt inclusion and host glass compositions from the eastern end of the Southwest Indian Ridge show a progressive depletion in light rare earth elements (LREE), Na8 and (La/Sm)n, but an increase in Fe8, from the NE (64°E) towards the SW (49°E). These changes indicate an increase in the degree of mantle melting towards the SW and correlate with a shallowing of the ridge axial depth and increase in crustal thickness. In addition, LREE enrichment in both melt inclusions and host glasses from the NE end of the ridge are compatible with re-fertilization of a depleted mantle source. The large compositional variations (e.g. P2O5 and K2O) of the melt inclusions from the NE end of the ridge (64°E), coupled with low Fe8 values, suggest that melts from the NE correspond to a variety of different batches of melts generated at shallow levels in the mantle melting column. In contrast, the progressively more depleted compositions and higher Fe8 values of the olivine- and plagioclase-hosted melt inclusions at the SW end of the studied region (49°E), suggest that these melt inclusions represent batches of melt generated by higher degrees of melting at greater mean depths in the mantle melting column. Systematic differences in Fe8 values between the plagioclase- and the olivine-hosted melt inclusions in the SW end (49°E) of the studied ridge area, suggest that the plagioclase-hosted melt inclusions represent final batches of melt generated at the top of the mantle melting column, whereas the olivine-hosted melt inclusions correspond to melts generated from less depleted, more fertile mantle at greater depths.

KEY WORDS: basalt; melt inclusions; olivine; plagioclase; Southwest Indian Ridge


    INTRODUCTION
 TOP
 ABSTRACT
 INTRODUCTION
 TECTONIC SETTING AND SAMPLING
 PETROGRAPHY AND MINERAL...
 ANALYTICAL TECHNIQUES
 PILLOW RIM GLASS AND...
 INTERPRETATION
 CONCLUSIONS
 SUPPLEMENTARY DATA
 REFERENCES
 
Melt inclusions are small aliquots of melt trapped in crystals. It is widely considered that melt inclusions preserve the compositional characteristics of early melts before they have mixed and fractionated in magma chambers. Studies of melt inclusions in mid-ocean ridge basalt (MORB) suggest that there is an extensive compositional range of mantle-derived melts under mid-ocean ridges (Sinton & Detrick, 1993Go; Sobolev & Shimizu, 1993Go, 1994Go; Sours-Page et al., 1999Go, 2002Go). These studies have shown that melt inclusion compositions vary with spreading rate, crustal thickness and deduced mantle temperature. Under slow-spreading ridges, where the degrees of mantle melting are lower (Reid & Jackson, 1981Go; McKenzie, 1985Go; Bown & White, 1994Go), the magma supply is episodic (Murton & Parson, 1993Go; Robinson, 1998Go), and steady-state magma chambers are rare (e.g. Fowler, 1976Go, 1978Go; Purdy & Detrick, 1986Go). Thus, the melts generated have less opportunity to mix, and any original diversity in melt composition is likely to be preserved. In contrast, under fast-spreading ridges, where the melt supply rate is higher, magma accumulates in more permanent, open-system magma chambers. Subsequent mixing results in a less diverse array of melt compositions preserved in melt inclusions (Sours-Page et al., 2002Go).

In this study, we use melt inclusions hosted in olivine and plagioclase phenocrysts from basalts erupted along a section (69°E–49°E) of the Southwest Indian Ridge (SWIR) in the Indian Ocean (Fig. 1), to test if the diversity of melts generated beneath the mid-ocean ridge varies with inferred changes in the melt flux. The depth of this section of the SWIR shallows from the NE to the SW and correlates with a change from tectonically dominated spreading (NE) to magmatically dominated spreading (SW). The depth also varies with inferred melt flux (Mendel et al., 1997Go).


Figure 1
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Fig. 1. Location and bathymetry map of the Southwest Indian Ridge between 70°E and 49°E. The profile of the axial depth of the ridge shows the ridge becomes shallower towards the SW emphasized by the arrow. The samples used for this study are marked by stars along the bathymetric profile. RTJ, Rodrigues Triple Junction; SEIR, Southeast Indian Ridge; CIR, Central Indian Ridge; BTJ, Bouvet Triple Junction; AAR, Australian–Antarctic Ridge.

 
Geochemical studies of lavas along the Southwest Indian Ridge show that they are chemically and isotopically different from Atlantic and Pacific MORB (Frey et al., 1980; Le Roex et al., 1983Go; Price et al., 1986Go; Mahoney et al., 1989Go; Natland, 1991Go; Meyzen et al., 2003Go). Along its length from 49°E towards the Rodrigues Triple Junction (RTJ) (70°E), the SWIR contains increasingly Na-rich basalts, some of which are the most Na-rich known from the global mid-ocean ridge system (Price et al., 1986Go; Natland, 1991Go; Meyzen et al., 2003Go). The most eastern samples also have high Fe8 and (La/Sm)n values. These geochemical features are consistent with lower melt fractions towards the SE, although Meyzen et al. (2003Go) also identified a component of mantle metasomatism affecting the source of samples east of 61°E.

Although trapped melts, melt inclusions rarely represent the unmodified composition of their host magma. Complications arise from crystallization of the host mineral on inclusion walls, and growth of daughter crystals within inclusions (Roedder, 1984Go). In the majority of melt inclusion studies, homogenization experiments are carried out to restore the composition of the melt inclusions to that at the moment of entrapment. However, a number of problems are associated with such homogenization experiments. Re-equilibration between melt inclusions and their hosts may occur as a result of slow heating, whereas rapid heating may provide an erroneous temperature of entrapment (Sours-Page et al., 1999Go; Danyushevsky et al., 2002Go). Some of these problems can be better controlled if the homogenization experiments are performed under visual control (Danyushevsky et al., 2002Go). An alternative method of reconstructing the composition of the melt inclusions at the moment of entrapment is to use numerical models, based on the composition of the residual melt in the inclusion, the equilibrium composition of the mineral host and the amount of post-entrapment crystallization (Danyushevsky et al., 2000Go; Gaetani & Watson, 2002Go). However, these models can only be applied if re-equilibration between the host and the melt inclusions did not occur during natural cooling and the melt inclusions remain glassy after eruption.

In this study we use numerically reconstructed melt inclusion compositions to investigate melt diversity and mantle processes at the SWIR. The olivine-hosted and plagioclase-hosted melt inclusions used for this study are all naturally glassy. Some, however, have host overgrowth on their walls. These overgrowths are not visible through the optical microscope, but their presence has been detected from the melt inclusion compositions. Inverse modelling is used to calculate the original composition of the melt inclusions at their moment of entrapment.


    TECTONIC SETTING AND SAMPLING
 TOP
 ABSTRACT
 INTRODUCTION
 TECTONIC SETTING AND SAMPLING
 PETROGRAPHY AND MINERAL...
 ANALYTICAL TECHNIQUES
 PILLOW RIM GLASS AND...
 INTERPRETATION
 CONCLUSIONS
 SUPPLEMENTARY DATA
 REFERENCES
 
The SWIR extends from the Bouvet Triple Junction (BTJ) (54°50'S, 00°40'W) in the South Atlantic Ocean to the Rodrigues Triple Junction (RTJ) (25°30'S, 70°00'E) in the Indian Ocean (Fig. 1). The SWIR is classified as an ultraslow-spreading centre (Dick et al., 2003Go). Its present-day full spreading rate varies along the ridge from ~16–18 mm/year in the SW to ~12–13 mm/year in the NE (Chu & Gordon, 1999Go). The NE end of the ridge propagates towards the RTJ and is offset by three major fracture zones oriented north–south (Scalter et al., 1981Go; de Ribet et al., 1988Go): the Gallieni Fracture Zone (52·5°E), the Atlantis II Fracture Zone (57°E) and the Melville Fracture Zone (61°E) (Fig. 1). These fracture zones divide the SWIR into three segments, which are characterized from SW to NE by a progressive decrease in the number of axial volcanoes and an increase of the mean axial depth of the ridge (Mendel et al., 1997Go; Cannat et al., 1999Go). This broad bathymetric variation suggests thinner crust and/or denser mantle towards the RTJ (Cannat et al., 1999Go; Sauter et al., 2001Go). Seismic studies between 61°E and 63°E along the SWIR (Muller et al., 1999Go, 2000Go) also suggest the presence of anomalously thin crust, about 4–5 km thick, and Mendel et al. (1997Go) and Cannat et al. (1999Go) suggested that these changes are consequences of a reduced melt supply in the NE part of the SWIR, possibly resulting from lower mantle temperatures compared with the SW part. Minshull & White (1996Go) and Robinson et al. (2001Go) have further suggested that the lower mantle temperature under the NE end of the SWIR is the result of conductive cooling of the asthenospheric mantle owing to slow upwelling.

The samples investigated for this study (DR16, DR27, DR28, DR51, DR61 and DR75) (Fig. 1) were dredged along the axis of the SWIR [during cruise EDUL Echantillonage d’une Dorsal UltraLente in 1997] (Fig. 1). They are selected from the three main ridge segments delimited by the Melville, Atlantis II and Gallieni fracture zones.


    PETROGRAPHY AND MINERAL CHEMISTRY
 TOP
 ABSTRACT
 INTRODUCTION
 TECTONIC SETTING AND SAMPLING
 PETROGRAPHY AND MINERAL...
 ANALYTICAL TECHNIQUES
 PILLOW RIM GLASS AND...
 INTERPRETATION
 CONCLUSIONS
 SUPPLEMENTARY DATA
 REFERENCES
 
The samples investigated are fragments of basaltic pillow lavas and sheet flows. They are porphyritic with plagioclase phenocrysts and olivine microphenocrysts in a glassy to cryptocrystalline matrix. Plagioclase is the dominant phenocryst phase. The matrix has a variolitic texture, varying from glassy quenched rims (1–10 mm thick) to more devitrified textures towards the interior of the samples. The matrix from the sample interior contains microcrystalline plagioclase, olivine and spinel with interstitial glass. Plagioclase and olivine crystals located in the rapidly quenched glassy pillow rims were selected for this study, as they are more likely to contain naturally occurring glassy melt inclusions with minimal post-entrapment modification. A total of 140 melt inclusions were analysed, of which 129 are plagioclase-hosted and 11 are olivine-hosted.

Olivine
Olivine occurs both as single euhedral to subhedral phenocrysts ranging in size from 1 mm to 100 µm, and in glomero-porphyritic aggregates along with plagioclase. Some of the olivines have partially resorbed rims whereas others contain spinel microlites and rare, glassy melt inclusions (Fig. 2a). Olivine compositions range from Fo81 (DR75) to Fo87 (DR28) (Table 1). The melt inclusions range from 5 to 80 µm in diameter, are rounded, and contain contraction bubbles.


Figure 2
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Fig. 2. (a) Glassy olivine-hosted melt inclusions from sample DR28. (b) Backscattered electron image of plagioclase-hosted melt inclusions from sample DR75. Both images illustrate melt inclusions typical of those analysed in this study. The mean size of the inclusions is 30 µm.

 

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Table 1: Olivine (Ol) and plagioclase (Pl) host phenocrysts compositions

 
Plagioclase
Plagioclase phenocrysts range in morphology from euhedral to subhedral shapes, and are between 2 and 20 mm in size. Many crystals have resorbed rims and some exhibit sieve textures. They occur as both single crystals and in glomero-porphyritic aggregates with olivine, and commonly contain olivine and spinel microlites, as well as abundant melt inclusions (Fig. 2b). The plagioclase crystals show normal, reverse and oscillatory zoning ranging from An89 (DR75) to An62 (DR28) (Table 1). The different zoning types occur in well-defined geographical regions along the SWIR: reverse zoning (i.e. more calcic rims) is typical to the NE of the Melville Fracture Zone (61°E); normal zoning to the SW of the Gallieni Fracture Zone (52°E); and oscillatory zoning mostly in the region between (Mével et al., 2002Go). The average anorthite content, which is variable for different crystals in the same sample, also varies with position along the SWIR, becoming progressively more anorthitic (more calcic) towards the SW (Table 1).

Primary, rounded, melt inclusions are abundant in nearly all plagioclase phenocrysts, (Fig. 2b). They range from 5 to 100 µm in diameter, are randomly arranged within the centre of the crystal, but commonly aligned parallel to zoning or parallel to twin planes, and usually contain contraction bubbles.


    ANALYTICAL TECHNIQUES
 TOP
 ABSTRACT
 INTRODUCTION
 TECTONIC SETTING AND SAMPLING
 PETROGRAPHY AND MINERAL...
 ANALYTICAL TECHNIQUES
 PILLOW RIM GLASS AND...
 INTERPRETATION
 CONCLUSIONS
 SUPPLEMENTARY DATA
 REFERENCES
 
The pillow rim glasses, the naturally glassy melt inclusions, and the host olivine and plagioclase phenocrysts were analysed for major elements using a Cameca SX100 electron microprobe at the Department of Earth Sciences, The Open University, UK. Pillow rim glasses and host crystals were analysed using an electron beam defocused to 20 µm to maximize the excitation volume while minimizing volatile loss, with an accelerating voltage of 15 kV and a current of 20 nA and an acquisition time of 10 s for each element. Calibration was made against internal standards and the drift was monitored using a naturally occurring kaersutite amphibole. The melt inclusions were analysed using an electron beam of 10 µm diameter because of the small size of the melt inclusions (~30 µm). Using such a small electron beam increases the volatile loss during analysis; however, volatile loss was considered negligible when the totals of the analyses were between 98·5% and 100%. The acquisition time for each element was 10 s.

The trace element and rare earth element (REE) compositions of pillow rim glasses, glassy melt inclusions and host phenocrysts were determined by ion microprobe analyses, using a Cameca ims-4f at the Department of Geology and Geophysics, University of Edinburgh, UK. The analyses were conducted using a primary beam of negatively charged oxygen ions with a current of 5 nA and net energy of 15 keV. The beam was focused to a spot 20 µm in diameter, which limited the analyses to only the larger melt inclusions (>35 µm). The secondary ions were measured using an energy filtering technique to suppress molecular ion interferences. Only ions of energy 55–75 eV were measured and detected using an electron multiplier. International standard glass BCR (Basalt, Columbia River) was used for the calibration of the matrix glasses, olivine and melt inclusion concentrations, and the SHF (Sapphire Hill Anorthoclase) plagioclase standard (Irving & Frey, 1984Go) was used for the calibration of plagioclase analyses. Reproducibility on the values of the BCR standard was better than 10%.


    PILLOW RIM GLASS AND MELT INCLUSION COMPOSITIONS
 TOP
 ABSTRACT
 INTRODUCTION
 TECTONIC SETTING AND SAMPLING
 PETROGRAPHY AND MINERAL...
 ANALYTICAL TECHNIQUES
 PILLOW RIM GLASS AND...
 INTERPRETATION
 CONCLUSIONS
 SUPPLEMENTARY DATA
 REFERENCES
 
Major elements
The pillow rim glasses show a general westward increase in FeO, TiO2 and CaO concentration and a decrease in Al2O3, Na2O and K2O, between 64°E and 49°E along the SWIR (Fig. 3; Table 2). At a local scale, however, at specific locations along the ridge, the glasses show large variations in TiO2, P2O5 and K2O (e.g. at 59°E). In the studied samples, pillow rim glasses at 55°E (DR61) have the highest concentration in TiO2 and P2O5 but the lowest in MgO compared with the host glasses from the rest of the studied samples. The observed major element trends can be reproduced by calculated fractional crystallization liquid lines of descent (LLD). The fractionation trends and the parental magmas (Table 3) were determined by reverse fractional crystallization calculations (using the program ‘Petrolog v.2’, Danyushevsky, 2001Go), involving the addition of olivine, plagioclase and clinopyroxene to the known composition of the pillow rim glasses, such that the final liquids are in equilibrium with mantle olivine (Fo90). Plagioclase fractionation was initiated when the liquids reached an MgO content of between 9 and 10 wt %; glasses with MgO <9–10 wt % define an olivine + plagioclase cotectic (Fig. 4).


Figure 3
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Fig. 3. Major element compositions vs longitude (°E) of Southwest Indian Ridge glasses (Meyzen et al., 2003Go) (•) compared with host glasses from this study ({square}).

 

Figure 4
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Fig. 4. TiO2 (a), Al2O3 (b) and Na2O (c) vs MgO wt % variation diagrams of melt inclusion compositions before recalculation ({blacktriangleup}), after recalculation (white circles in a square frame) and host glass ({diamondsuit}). A small number of recalculated melt inclusion compositions still have anomalous compositions. These are discarded from subsequent consideration. Also shown are global MORB glass compositions (•) (Smithsonian Institution Catalogue, available at www.minerals.si.edu/research/glass/), Southwest Indian Ridge glass compositions (Meyzen et al., 2003Go) ({square}) and liquid line of descent (calculated using the program ‘Petrolog v.2, Danyushevsky, 2001Go) (+).

 

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Table 2: Host glass composition of samples from the Southwest Indian Ridge between 64°E and 49°E

 

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Table 3: Calculated parental melt composition

 
The olivine-hosted melt inclusions are characterized by low MgO and high Al2O3 concentrations compared with the pillow rim glasses. Plagioclase-hosted melt inclusions are generally characterized by large variations in MgO, Al2O3, TiO2 and FeO compared with the host glasses (Fig. 4 and Table 4). The variations in MgO and Al2O3 in naturally glassy melt inclusions indicate post-entrapment crystallization of the host crystal on the walls of the inclusion, resulting in compositions that are depleted in elements that are compatible with the host crystal (e.g. MgO for olivine and Al2O3 for plagioclase). The composition of the melt inclusion at the moment of entrapment was estimated by calculating the reverse of the host crystallization on the walls of the inclusion until the composition reached the olivine + plagioclase cotectic (Fig. 4 and Table 5). The recalculated melt inclusion compositions plot consistently along the liquid line of descent on the MgO vs Al2O3 diagram. However, for other major elements (e.g. TiO2 and Na2O) some of the reconstructed melt inclusion compositions plot outside the LLD defined by the glasses. There are melt inclusions that are low in TiO2 and FeO compared with the host glass, and that remain low after recalculation. They also show anomalous concentrations in other major elements (e.g. Na2O) and plot outside the general MORB field (Fig. 4). These extraordinary compositions have been discarded from subsequent interpretations as we believe they do not represent the composition of any possible mantle-derived melt and are products of additional post-entrapment processes. Figure 4 illustrates the compositional differences before and after correction for the olivine- and plagioclase-hosted melt inclusions from sample DR28.


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Table 4: Representative uncorrected olivine- and plagioclase-hosted melt inclusions compositions from samples of the Southwest Indian Ridge (64°E49°E)

 

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Table 5: Corrected olivine and plagioclase hosted melt inclusions compositions from samples of the Southwest Indian Ridge (64°E49°E)

 
The non-discarded recalculated olivine- and plagioclase-hosted melt inclusion compositions (Table 5) have been plotted against longitude (Fig. 5), where they follow the general trend displayed by the host glasses. The melt inclusions show large compositional ranges in K2O and P2O5, particularly those in samples collected from locations between 64°E and 61°E (Fig. 5). Some of the recalculated compositions of plagioclase-hosted melt inclusions from samples at 61°E (DR27 and DR28) and 49°E (DR75) have lower concentrations of FeO and TiO2 compared with the olivine-hosted melt inclusions and host glass compositions (Fig. 5).


Figure 5
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Fig. 5. Major element diagrams vs longitude (°E) of recalculated olivine-hosted melt inclusion compositions ({diamondsuit}), recalculated plagioclase-hosted melt inclusion compositions ({triangleup}), host glasses ({square}) and Southwest Indian Ridge glass data (Meyzen et al., 2003Go) (Figure 5).

 
Trace elements
The melt inclusions show a general westward decrease in enrichment of light REE (LREE) relative to heavy REE (HREE) (Fig. 6). Those from samples collected between 64°E–61°E (DR16–DR28) and 55°E (DR51) are more enriched in LREE compared with the melt inclusions at 55°E (DR51) and at 49°E (DR75).


Figure 6
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Fig. 6. Chondrite-normalized (Sun & McDonough, 1989Go) REE patterns of host glasses and melt inclusions for different locations along the SWIR.

 

    INTERPRETATION
 TOP
 ABSTRACT
 INTRODUCTION
 TECTONIC SETTING AND SAMPLING
 PETROGRAPHY AND MINERAL...
 ANALYTICAL TECHNIQUES
 PILLOW RIM GLASS AND...
 INTERPRETATION
 CONCLUSIONS
 SUPPLEMENTARY DATA
 REFERENCES
 
Melt inclusion compositional variations
The recalculated major element concentrations of the olivine-hosted and plagioclase-hosted melt inclusions display a similar trend to that shown by the SWIR glasses (Fig. 5). Both matrix glasses and melt inclusions decrease in Al2O3, Na2O and K2O concentration, but increase in FeO and CaO, from the NE (64°E) to the SW (49°E) along the SWIR. This suggests an increase in the degree of fractional crystallization of the melt towards the SW. Some recalculated plagioclase-hosted melt inclusion compositions, particularly those from sample DR75 at 49°E, are low in FeO and TiO2 compared with the matrix glass and olivine-hosted melt inclusions. Danyushevsky et al. (2002Go) described the low TiO2 and FeO contents of such melt inclusions as a common feature in MORB, and suggested that they are caused by pre-eruption re-equilibration by diffusion of Fe and Ti out of the melt inclusions into the host plagioclase, and diffusion of Si from the host into the melt inclusions. In contrast, Kohut & Nielsen (2004Go) demonstrated that depletions in Fe–Ti and the large K2O variability observed in natural MORB melt inclusions hosted in An-rich plagioclase phenocrysts are not the product of post-entrapment processes. Their experimental results imply that the compositional variability observed in the melt inclusions reflects melt trapped at earlier stages. Thus, the compositional diversity in the melt inclusions represents trapped host melt that changed in composition with time and increasing crystallization, and that the final host lava composition is the result of the complete mixing of a number of compositionally diverse magma batches. From this, it follows that the compositional variability of the melt inclusion compositions in this study are likely to represent the original diversity of melts present in the magma storage system. The fact that some melt inclusions plot outside the liquid lines of descent of the host glasses for some major elements, but within the SWIR and the MORB field (Fig. 4c), is evidence for a diversity of parental melts. The accumulation and mixture of all these melts result in the final host lava composition.

Other studies (Nielsen & Sours-Page, 2000Go; Michael et al., 2002Go) have shown that plagioclase-hosted melt inclusions can also display depletions in high field strength elements (HFSE) and HREE relative to the host glasses, similar to the depletions observed in the discarded melt inclusions in this study (Table 4 and Supplementary Data Appendix 1, available for downloading at http://www.petrology.oxfordjournals.org). Michael et al. (2002Go) suggested that the HFSE depletion in plagioclase-hosted melt inclusions is caused by dissolution of plagioclase to form a melt that is depleted in such elements. Diffusion through the walls of the plagioclase host then moves the inclusion compositions towards that of the external melt, with fast diffusing elements equilibrating before the slower diffusing HFSE. In contrast, Nielsen & Sours-Page (2000Go) proposed a hydrothermally altered, depleted peridotite source for the melt trapped in these depleted melt inclusions. The discarded plagioclase-hosted melt inclusions in this study, which plotted outside the MORB and SWIR glass field and are characterized by very low Fe–Ti and HREE but high Na, probably represent melts that were formed by the mixture of the originally entrapped melt and dissolved host plagioclase.

Indicators of melt fraction, depth of melting and source composition
To account for the effects of fractional crystallization on both melt inclusions and matrix glass, the major element data are normalized to 8 wt % MgO [following the method of Klein & Langmuir (1987Go)]. The Na8 and K8 values are used to estimate the degree of melting generated at mid-ocean ridges (Klein & Langmuir, 1987Go; Langmuir et al., 1992Go); both Na and K behave incompatibly during partial melting, and are therefore preferentially partitioned into the melt at low degrees of melting. Other incompatible trace elements, including the REE, which are partitioned into the melt, also act as indicators of the degree of partial melting [e.g. (La/Sm)n]. Parameters such as Fe8 are used as indicators of the depth of melting (Klein & Langmuir, 1987Go; Langmuir et al., 1992Go).

The host glasses and melt inclusions show a decrease in Na8 and K8 values and a corresponding increase in Fe8 values, from 64°E to 49°E (Fig. 7). Klein & Langmuir (1987Go) suggested that a progressive decrease in Na8 indicates an increase in degree of partial melting of a spinel lherzolite mantle source, whereas an increase in Fe8 indicates an increase in average depth of melting. Thus, the decrease in Na8 for both the host glasses and melt inclusions towards 49°E suggests an increase in the degree of partial melting towards the SW part of the SWIR (64°E–49°E). Similarly, the increasing Fe8 shown by the host glasses and the melt inclusions towards 49°E suggests greater average depth of melting to the SW of the SWIR and, hence, a higher mantle temperature. This is consistent with a NE to SW regional increase in axial depth along the SWIR (Cannat et al., 1999Go) and an increase in the abundance of volcanoes within the area (Mendel et al., 1997Go), and it is evidence for the increasing temperature of the underlying mantle (Sauter et al., 2001Go).


Figure 7
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Fig. 7. Na8 (a), Fe8 (b) and K8 (c) vs longitude. Symbols as in Fig. 5.

 
East of the Melville FZ, the olivine- and plagioclase-hosted melt inclusions have low Fe8 (Fig. 7); in contrast, their Na8 values are much higher, and show a large variation (Fig. 7). The low Fe8 values suggest that these melt inclusions are segregated at relatively shallow depths in the melting column, whereas the high, but diverse, Na8 values indicate melt segregation at low degrees of melting. West of the Melville FZ, the melt inclusions show a progressive increase (with increasing distance to the west from the Melville FZ) in Fe8 variability, with those hosted within olivine having progressively higher Fe8 values compared with those hosted in plagioclase. This suggests that the olivine-hosted melt inclusions were segregated from the mantle at a greater average depth than the plagioclase-hosted melt inclusions. This is consistent with the depleted compositions of the plagioclase-hosted melt inclusions (e.g. from the samples at 57°E and 49°E), and their shallow depth of melting, compared with the olivine-hosted melt inclusions. The Fe8 values and depleted compositions indicate that these shallow melts represent some of the last melt fractions produced from the mantle column.

The basaltic glasses from the SWIR between 64°E and 49°E have previously been reported to form two distinct compositional groups, distinguished by their Na8, Fe8 and trace elements ratios [such as (Sm/Yb)n; see Meyzen et al., 2003Go]. These two compositional domains, separated by the Melville FZ (Mendel et al., 1997Go; Meyzen et al., 2003Go) have been attributed to compositional differences in the mantle source beneath the NE end of the SWIR. It has been suggested that the mantle source to the east of the Melville FZ is depleted in clinopyroxene as a consequence of partial melting followed by refertilization of the depleted source, generating the enrichment in LREE and Na observed in the lavas from this region. To the west of the Melville FZ, the composition of the glasses is consistent with a progressive increase, from NE to SW, in the degree of partial melting of a refertilized lherzolite source (Meyzen et al., 2003Go). The Na8 and Fe8 values of the melt inclusions also separate into the two compositional groups defined by the SWIR glasses (Fig. 8), with higher Na8 values to the east of the Melville fracture zone, and higher Fe8 to the west. The chondrite-normalized REE patterns of melt inclusions (Fig. 8) from samples between 64°E and 61°E (east of the Melville FZ) show LREE enrichment but slight depletion in HREE, suggesting that the melt inclusions were derived from a source previously melted to relatively high degrees to the point where the source became depleted in clinopyroxene and was subsequently refertilized, becoming enriched in LREE. The higher Na8 of these melt inclusions, which agrees with the glass data, also suggests that the source has been refertilized as indicated by Meyzen et al. (2003Go). None of the SWIR melt inclusion REE patterns appear to be as depleted as those of the Mid-Atlantic Ridge ultra-depleted olivine-hosted melt inclusions studied by Sobolev & Shimizu (1993Go) (Fig. 8), suggesting that complete exhaustion of clinopyroxene in the source did not occur.


Figure 8
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Fig. 8. Longitudinal Fe8 vs Na8 variation of recalculated melt inclusion compositions and chondrite-normalized REE patterns of melt inclusions compared with the MORB field and ultra-depleted olivine-hosted melt inclusions from the Mid-Atlantic Ridge (MAR) (Sobolev & Shimizu, 1993Go). Symbols as in Fig. 5.

 
Melt inclusions from samples at 57°E (DR51) and 49°E (DR75), west of the Melville FZ, are depleted in LREE with respect to the HREE (Figs 6 and 8). The more strongly depleted REE patterns of the melt inclusions in sample DR75 compared with sample DR51 suggest an increase in the degree of partial melting westwards along the SWIR. However, melt inclusions from sample DR61 located at 55°E, west of the Melville FZ, also show enrichment in LREE similar to the samples to the east of the Melville FZ, but have flat patterns for the HREE, suggesting that the melt source is not depleted in clinopyroxene (Fig. 6). The similarities in composition of the melt inclusions from sample DR61 at 55°E to the samples east of Melville FZ suggest that these melts are also derived from a source that has been enriched in LREE, probably by the same metasomatic fluids that affected the source region to the east of Melville FZ. This interpretation is supported by variations in trace element ratios such as (La/Sm)n, which are also indicators of variations in the degree of mantle partial melting and/or source composition.

From the NE to the SW part of the SWIR, the host glasses and melt inclusions show a general decrease in (La/Sm)n. This is consistent with an increase in the degree of partial melting towards the SW (Fig. 9). However, melt inclusions and matrix glass from sample DR61 have higher (La/Sm)n values compared with samples DR51 and DR75. This indicates, despite the general decrease in trace element ratios, that there is local magma enrichment.


Figure 9
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Fig. 9. Chondrite-normalized (La/Sm)n (Sun & McDonough 1989Go) vs longitude (°E). Symbols as in Fig. 5.

 
The model proposed in this study to explain the compositional differences observed in the melt inclusions and host glasses is summarized in Fig. 10. The degree of partial melting, between 70°E and 49°E along the SWIR, increases from NE to SW. Melts east of the Melville FZ are generated at shallow depths in the mantle melting column. Melts west of the Melville FZ, initially generated deep in the mantle melting column, become trapped within olivine when they reach the magma chamber. As mantle melting continues, melts from the shallower, depleted parts of the mantle melting column are removed and arrive in the magma chamber. By this time plagioclase is crystallizing in the magma chamber and these shallow depleted melts become trapped. The compositional diversity observed in melts from the east of the Melville FZ also suggests episodic magma supply and low degrees of mantle melting.


Figure 10
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Fig. 10. Schematic illustration of the variation in depth of melt segregation in the mantle melting column and melt inclusion entrapment along the SWIR between 70°E and 49°E.

 

    CONCLUSIONS
 TOP
 ABSTRACT
 INTRODUCTION
 TECTONIC SETTING AND SAMPLING
 PETROGRAPHY AND MINERAL...
 ANALYTICAL TECHNIQUES
 PILLOW RIM GLASS AND...
 INTERPRETATION
 CONCLUSIONS
 SUPPLEMENTARY DATA
 REFERENCES
 
Olivine- and plagioclase-hosted melt inclusions from the 64°E–49°E region of the Southwest Indian Ridge show an increase in the degree of fractional crystallization towards the SW. Melt inclusions from the NE end of the ridge (64°E–61°E) exhibit more compositional diversity compared with those from the SW (55°E–49°E). Like their host glasses, the melt inclusions also have increasing Na8 and decreasing Fe8 values to the NE. This suggests that the ridge in this region is supplied by a range of different melt batches generated by low degrees of melting at shallow levels within a spinel lherzolite source. However, towards the SW, where the ridge is supplied by higher degree melts and the melt compositions become progressively more depleted in LREE, local enrichments of the melt source also occur. This is shown by melt inclusions from sample DR61 at 57°E, in which LREE-enriched compositions are superimposed on low Na8 and high Fe8 LREE-depleted compositions. The depleted composition of plagioclase-hosted melt inclusions from sample DR75 at 49°E indicates that these melts are the last melts segregated from a depleted source at very shallow levels.

The olivine-hosted melt inclusions typically show similar compositions to the host glasses but, compared with plagioclase-hosted melt inclusions, they show progressively higher Fe8 values towards the SW end of the ridge, with the greatest variation at 49°E. This suggests that the olivine-hosted melt inclusions represent melt batches that were formed at a greater depth than the plagioclase-hosted ones.


    SUPPLEMENTARY DATA
 TOP
 ABSTRACT
 INTRODUCTION
 TECTONIC SETTING AND SAMPLING
 PETROGRAPHY AND MINERAL...
 ANALYTICAL TECHNIQUES
 PILLOW RIM GLASS AND...
 INTERPRETATION
 CONCLUSIONS
 SUPPLEMENTARY DATA
 REFERENCES
 
Supplementary data for this paper are available at Journal of Petrology online.


    ACKNOWLEDGEMENTS
 
We wish to thank Leonid Danyushevsky, Peter Michael and Jon P. Davidson for their helpful reviews, and editor M. Wilson for the helpful comments and suggestions. This paper is part of L. Font's Ph.D. thesis supported by a Ph.D. scholarship from the University of Southampton and the School of Ocean and Earth Sciences. The ion microprobe analyses were supported by the NERC grant IMP181/1001.


*Corresponding author. Present address: Department of Earth Sciences, Science Laboratories, University of Durham, Durham DH1 3LE, UK. Telephone: +44 (0)1913342329. Fax: +44 (0) 3342301. E-mail: laura.font{at}durham.ac.uk


    REFERENCES
 TOP
 ABSTRACT
 INTRODUCTION
 TECTONIC SETTING AND SAMPLING
 PETROGRAPHY AND MINERAL...
 ANALYTICAL TECHNIQUES
 PILLOW RIM GLASS AND...
 INTERPRETATION
 CONCLUSIONS
 SUPPLEMENTARY DATA
 REFERENCES
 
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Melt Inclusions in Basaltic and Related Volcanic Rocks
Reviews in Mineralogy and Geochemistry, January 1, 2008; 69(1): 273 - 331.
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