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Journal of Petrology Volume 42 Number 11 Pages 2033-2048 2001
© Oxford University Press 2001

A Geochemical Classification for Granitic Rocks

B. RONALD FROST1,*, CALVIN G. BARNES2, WILLIAM J. COLLINS3, RICHARD J. ARCULUS4, DAVID J. ELLIS4 and CAROL D. FROST1

1DEPARTMENT OF GEOLOGY AND GEOPHYSICS, UNIVERSITY OF WYOMING, LARAMIE, WY 82071, USA
2DEPARTMENT OF GEOSCIENCES, TEXAS TECH UNIVERSITY, LUBBOCK, TX 79409, USA
3DEPARTMENT OF GEOLOGY, UNIVERSITY OF NEWCASTLE, NEWCASTLE, N.S.W. 2308, AUSTRALIA
4DEPARTMENT OF GEOLOGY, AUSTRALIAN NATIONAL UNIVERSITY, CANBERRA, A.C.T. 0200, AUSTRALIA

This geochemical classification of granitic rocks is based upon three variables. These are FeO/(FeO + MgO) = Fe-number [or FeOtot/(FeOtot + MgO) = Fe*], the modified alkali–lime index (MALI) (Na2O + K2O – CaO) and the aluminum saturation index (ASI) [Al/(Ca – 1·67P + Na + K)]. The Fe-number (or Fe*) distinguishes ferroan granitoids, which manifest strong iron enrichment, from magnesian granitoids, which do not. The ferroan and magnesian granitoids can further be classified into alkalic, alkali–calcic, calc-alkalic, and calcic on the basis of the MALI and subdivided on the basis of the ASI into peraluminous, metaluminous or peralkaline. Because alkalic rocks are not likely to be peraluminous and calcic and calc-alkalic rocks are not likely to be peralkaline, this classification leads to 16 possible groups of granitic rocks. In this classification most Cordilleran granitoids are magnesian and calc-alkalic or calcic; both metaluminous and peraluminous types are present. A-type granitoids are ferroan alkali–calcic, although some are ferroan alkalic. Most are metaluminous although some are peraluminous. Caledonian post-orogenic granites are predominantly magnesian alkali–calcic. Those with <70 wt % SiO2 are dominantly metaluminous, whereas more silica-rich varieties are commonly peraluminous. Peraluminous leucogranites may be either magnesian or ferroan and have a MALI that ranges from calcic to alkalic.

KEY WORDS: batholiths; granite; granitoid; igneous petrology; rock classification


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