Journal of Petrology Advance Access originally published online on March 30, 2006
Journal of Petrology 2006 47(7):1439-1465; doi:10.1093/petrology/egl018
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Comparison of 40Ar39Ar and RbSr Data on Phengites from the UHP BrossascoIsasca Unit (Dora Maira Massif, Italy): Implications for Dating White Mica
1 ISTITUTO DI GEOSCIENZE E GEORISORSECNR VIA MORUZZI 1, I-56124 PISA, ITALY
2 ISTITUTO DI GEOSCIENZE E GEORISORSECNR, SEZIONE DI TORINO VIA VALPERGA CALUSO 35, I-10125 TORINO, ITALY
3 DIPARTIMENTO DI SCIENZE MINERALOGICHE E PETROLOGICHE VIA VALPERGA CALUSO 35, I-10125 TORINO, ITALY
4 ISTITUTO DI GEOSCIENZE E GEORISORSECNR, SEZIONE DI PAVIA VIA FERRATA 1, I-27100 PAVIA, ITALY
RECEIVED JULY 31, 2005; ACCEPTED MARCH 7, 2006
Different lithologies (impure marble, eclogite and granitic orthogneiss) sampled from a restricted area of the coesite-bearing BrossascoIsasca Unit (Dora Maira Massif) have been investigated to examine the behaviour of 40Ar39Ar and RbSr systems in phengites developed under ultrahigh-pressure (UHP) metamorphism. Mineralogical and petrological data indicate that zoned phengites record distinct segments of the PT path: prograde, peak to early retrograde in the marble, peak to early retrograde in the eclogite, and late retrograde in the orthogneiss. Besides major element zoning, ion microprobe analysis of phengite in the marble also reveals a pronounced zoning of trace elements (including Rb and Sr). 40Ar39Ar apparent ages (
3562 Ma, marble;
89170 Ma, eclogite;
3552 Ma, orthogneiss), determined through Ar laserprobe data on phengites (step-heating and in situ techniques), show wide intra-sample and inter-sample variations closely linked to within-sample microchemical variations: apparent ages decrease with decreasing celadonite contents. These data confirm previous reports on excess Ar and, more significantly, highlight that phengite acted as a closed system in the different lithologies and that chemical exchange, not volume diffusion, was the main factor controlling the rate of Ar transport. Conversely, a RbSr internal isochron from the same eclogite yields an age of
36 Ma, overlapping with the time of the UHP metamorphic peak determined through UPb data and thereby corroborating the previous conclusion that UHP metamorphism and early retrogression occurred in close succession. Different phengite fractions of the marble yield calcitephengite isochron ages of
36 to
60 Ma. Although this time interval matches Ar ages from the same sample, RbSr data from phengite are not entirely consistent with the whole dataset. According to trace element variations in phengite, only RbSr data from two wet-ground phengite separates, yielding ages of
36 and
41 Ma, are internally consistent. The oldest age obtained from a millimetre-sized grain fraction enriched in progradepeak phengites may represent a minimum age estimate for the prograde phengite relics. Results highlight the potential of the in situ 40Ar39Ar laser technique in resolving discrete PT stages experienced by eclogite-facies rocks (provided that excess Ar is demonstrably a negligible factor), and confirm the potential of RbSr internal mineral isochrons in providing precise crystallization ages for eclogite-facies mineral assemblages.
KEY WORDS: 40Ar39Ar dating; RbSr dating; phengite; SIMS; UHP metamorphism
*Corresponding author. Fax: +39 050 3152360. E-mail: g.divincenzo{at}igg.cnr.it
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